个人简介:曹勇勇,博士,副教授,硕士生导师,嘉兴市精英引领计划入选者。2020年博士毕业于浙江工业大学,同年加入嘉兴学院工作,2017年曾赴美国俄克拉荷马大学交流访学一年。目前主要从事单双原子电催化氧还原反应(ORR)、氮还原反应(NRR)、二氧化碳还原反应(CO2RR)和尿素合成的实验和理论研究。现主持国家自然科学青年基金项目1项,浙江省一般项目1项,嘉兴市精英.引领领军人才项目1项,嘉兴市公益基金项目1项,企业横向项目4项;转让软件著作权一项金额5万元。以第一作者或通讯作者身份发表在J. Mater. Chem. A,Inorg. Chem,Chem. Commun,ACS Appl. Mater. Interfaces,J. Colloid. Inter. Sci, Green. Ener. Environ,Nanotechnology,Adv. Theor. Simu.等期刊发表论文30余篇。现主要从事化工原理课程的教学工作,指导本科生获得国家级竞赛三等奖4项,省级二等奖1项,省级三等奖3项。指导本科生获得浙江省新苗项目1项,SRT项目两项,指导本科生以第一作者发表SCI论文2篇。
主持项目:
1. 解质溶液局域环境下电催化合成双氧水的理论模拟,国家青年基金项目,2022.01-2024.12.(主持人)
2. 真实电解质溶液环境下电催化合成尿素的理论模拟,浙江省一般项目,2024.01-2026.12(主持人)
3. 电催化双氧水催化剂的智能设计和产品化,嘉兴市公益项目,2023.01-2025.12(主持人)
4. 高效双氧水电催化剂的开发和规模化生产,嘉兴市青年领军项目,2022.01 -2025.12(主持人)
5. 风机表面防腐关键技术应用,浙江犇通风机有限公司,2023.03-2025.03(主持人)
6. 高效防火型装配式墙体建筑材料的设计及技术研发,2023.07-2024.04(主持人)
7. 高附着力面料印花染料开发和设备技术改进研发及应用,2023.08-2024.08(主持人)
代表论文(近五年):
[1] Yongyong Cao, Yuxiao Meng, Yuting Wu, Hongjie Huang, Weichan Zhong, Zhangfeng Shen, Qineng Xia, Yangang Wang and Xi Li. Metal-free boron nanosheet as “buffer electron pool” for urea and ethanol synthesis via C–N and C–C coupling. J. Mater. Chem. A, 2022, 10, 23843-23853.
[2] Yuxiao Meng, Zhangmeng Xu, Zhangfeng Shen, Qineng Xia, Yongyong Cao*, Yangang Wang * and Xi Li*, Understanding the water molecule effect in metal-free B-based electrocatalysts for electrochemical CO2 reduction. J. Mater. Chem. A, 2022,10, 6508-6522.
[3] Yongyong Cao, Yuxiao Meng, Yuting Wu, Zhangfeng Shen, Qineng Xia, Hong Huang, Jian-Ping Lang, Hongwei Gu, Yangang Wang,* and Xi Li*, Regulation of the Coordination Structures of Transition Metals on Nitrogen-Doped Carbon Nanotubes for Electrochemical CO2 Reduction. Inorg. Chem. 2022, 61, 18957−18969
[4] Fucheng Wang, Yuxiao Meng, Xuanqi Chen, Lu Zhang, Guohua Li, Zhangfeng Shen, Yangang Wang*, Yongyong Cao*, Effect of Nickel-based Electrocatalyst size on Electrochemical Carbon Dioxide Reduction: A Density Functional Theory Study, 2022, J. Coll, Inter, Sci. 615, 587–596.
[5] Zhangxin Chen, Jiajie Cao, Xiaohui Wu, Dongqin Cai, Minghui Luo, Shuyu Xing, Xiuli Wen, Yongyin Chen, Yanxian Jin*, Dan Chen, Yongyong Cao*, Lingmin Wang, Xianqiang Xiong, and Binbin Yu*, B, N Co-Doping Sequence: An Efficient Electronic Modulation of thePd/MXene Interface with Enhanced Electrocatalytic Properties for Ethanol Electrooxidation, ACS Appl. Mater. Interfaces, 2022, 14, 12223−12233.
[6] Mengmeng Shao, Haodeng Chen, Yongyong Cao*, Shushu Fu, Shiji Hao, Min Chen, Jutao Jin, Wenlong Wang, Yunhui Wu and Lifeng Cui*, Phase transition in V-doped cobalt hydroxide for a superior alkaline hydrogen evolution reaction, Chem. Commun., 2022, 58, 12859
[7] Yongyong Cao, JinYan Zhao, Xing Zhong, Guilin Zhuang, Shengwei Deng, Zhongzhe Wei, Zihao Yao, Jianguo Wang*, Building highly active hybrid double–atom sites in C2N for enhanced electrocatalytic hydrogen peroxide synthesis, Green Ene. Envir, 2021, 6, 846–857.
[8] Yongyong Cao, Guobing Zhou, Xianlang Chen, Qi Qiao, Chenxia Zhao, Xiang Sun, Xing Zhong,Guilin Zhuang, Shengwei Deng, Zhongzhe Wei, Zihao Yao, Liangliang Huang* and Jianguo Wang*. Hydrogen Peroxide Synthesis on Porous Graphitic Carbon Nitride Using Water as Hydrogen Source. J. Mater. Chem. A, 2020, 8, 124-137.
[9] Yongyong Cao, Chenxia Zhao, Qiaojun Fang, Xing Zhong, Guilin Zhuang, Shengwei Deng, Zhongzhe Wei, Zihao Yao and Jianguo Wang*. Hydrogen Peroxide Electrochemical Synthesis on Hybrid Double-Atoms (Pd-Cu) doped N vacancy g-C3N4: A Novel Design Strategy for Electrocatalysts Screening. J. Mater. Chem. A, 2020, 8, 2672-2683.
[10] Yongyong Cao, Shengwei Deng*, Qiaojun Fang, Xiang Sun, ChenXia Zhao, Jingnan Zheng, Yijing Gao, Han Zhuo, Yuejin Li,Zihao Yao, Zhongzhe Wei, Xing Zhong, Guilin Zhuang and Jianguo Wang*. Single and double boron atoms doped nanoporous C2N−h2D electrocatalysts for highly efficient N2 reduction reaction: A density functional theory study. Nanotechnology, 2019, 30, 335403.
[11] Yongyong Cao, Zhao, JY, Zhong, X, Zhuang, GL, Deng, SW, Wei, ZZ, Yao, ZH, Wang, JG.* Building highly active hybrid double-atom sites in C2N for enhanced electrocatalytic hydrogen peroxide synthesis, GREEN ENERGY & ENVIRONMENT, 2021, 6(6), 846-857
[12] Yongyong Cao, Yijing Gao, Hu Zhou, Xianlang Chen, Hui Hu, Shengwei Deng, Xing Zhong, Guilin Zhuang and Jianguo Wang*. High Efficient Ammonia Synthesis Electrocatalyst: Single Ru Atom on Naturally Nanoporous Carbon Materials. Adv. Theory Simul. 2018, 1800018.
[13] 曹勇勇, 蒋军辉, 倪哲明*, 夏盛杰, 钱梦丹, 薛继龙. Au19Pt 团簇性质及对肉桂醛选择性加氢机理研究. 高等学校化学学报,2016,7, 1342-1350.
[14] Meng, YX,Xu, ZM,Shen, ZF,Xia, QN,Yongyong Cao *,Wang, YG*,Li, X*.Understanding the water molecule effect in metal-free B-based electrocatalysts for electrochemical CO2 reduction[J], J. Mater. Chem. A, A, 2022,10(12), 6508-6522.
[15] Chen, ZX, Cao, JJ, Wu, XH, Cai, DQ, Luo, MH, Xing, SY, Wen, XL, Chen, YY, Jin, YX, Chen, D, Yongyong Cao *, Wang, LM, Xiong, XQ, Yu, BB. B, N Co-Doping Sequence: An Efficient Electronic Modulation of the Pd/MXene Interface with Enhanced Electrocatalytic Properties for Ethanol Electrooxidation[J], ACS APPLIED MATERIALS & INTERFACES, 14(4), 12223-12233
[16] Wang, FC; Meng, YX ; Chen, XQ; Zhang, L; Li, GH; Shen, ZF ; Wang, YG; Yongyong Cao *, Effect of nickel-based electrocatalyst size on electrochemical carbon dioxide reduction: A density functional theory study[J], JOURNAL OF COLLOID AND INTERFACE SCIENCE, 615, 587-596
[17] Qiaoqiao Zhang, Yongyong Cao(共同一作), Yilong Yan, Bowen Yuan, Haiyang Zheng, Yu Gu, Xing Zhong and Jianguo Wang*. Synergetic Effect of Pyrrolic-N and Doped Boron in Mesoporous Carbon for Electrocatalytic Ozone production. J. Mater. Chem. A, 2020, 8, 2336-2342.
[18] Ziying Yuan, Yongyong Cao*, Yue Meng, Guoxiang, Yifan Zheng , Zheming Ni, Shengjie Xia*. The construction of lattice-matched CdS-Ag2S heterojunction photocatalysts: High-intensity built-in electric field effectively boosts bulk-charge separation efficiency. J. Hazard. Mater. 2023, 458, 131895.
[19] Zhangxin Chen, Jiajie Cao, Xiaohui Wu, Dongqin Cai, Minghui Luo, Shuyu Xing, Xiuli Wen, Yongyin Chen, Yanxian Jin,* Dan Chen, Yongyong Cao*, Lingmin Wang, Xianqiang Xiong, and Binbin Yu*. B, N Co-Doping Sequence: An Efficient Electronic Modulation of the Pd/MXene Interface with Enhanced Electrocatalytic Properties for Ethanol Electrooxidation. ACS Appl. Mater. Interfaces. 2022, 14, 12223−12233.
[20] Qiaoqiao Zhang,‡ Yongyong Cao,‡ Yilong Yan, Bowen Yuan, Haiyang Zheng, Yu Gu, Xing Zhong* and Jianguo Wang*. Synergetic effect of pyrrolic-N and doped boron in mesoporous carbon for electrocatalytic ozone production. J. Mater. Chem. A. 2020, 5.
[21] Shaoda Huang, Shuanglong Lu*, Yiming Hu, Yongyong Cao*, Yang Li, Fang Duan, Han Zhu, Yinghua Jin, Mingliang Du* and Wei Zhang*. Covalent Organic Frameworks with Molecular Electronic Modulation as Metal-Free Electrocatalysts for Efficient Hydrogen Peroxide Production. Small Struct. 2023, 2200387.
[22] Mengmeng Shao*, Shushu Fu, Yongyong Cao*, Shiji Hao, Haifeng Dang, Min Chen, Jutao Jin, Wenlong Wang, Jiaxing Wang, Lina Zuo, Dexing Zhang, and Xiaoji Wang*. Phase-Engineered Robust Cocatalyst of NiFe Bicarbonate with Pt Dopant for Enhanced Photocatalytic Water Splitting. Chem Asian J. 2023, e202300263.
[23] Mengmeng Shao*, Haodeng Chen, Yongyong Cao*, Shushu Fu, Shiji Hao, Min Chen,a Jutao Jin, Wenlong Wang, Yunhui Wu and Lifeng Cui*. Phase transition in V-doped cobalt hydroxide for a superior alkaline hydrogen evolution reaction. Chem. Commun., 2022,58, 12859.
授权专利:
钟兴, 王建国, 曹勇勇. 一种基于氧化铂合金负载硼,氮掺杂金刚石的催化剂及其制备方法和应用. 中国,CN 109112571 B,2019.10.01(授权)
本专利已经成功转让企业,转让金额高达1008万元。
转让软著:
单原子催化剂O2吸附自动建模及双 氧水过电势机器学习预测集成系统 _V1.0 (5万元)
获奖情况:
1. 获IOP出版社旗下期刊本年度的“中国高被引文章奖”;
2. 获浙江省优秀博士论文提名奖;
3. 获2023年嘉兴学院优秀党员称号
4. 获2023年嘉兴学院优秀毕业论文指导老师称号
联系方式:
Email: cyy@zjxu.edu.cn